Pickup On Demand is a one-time arrangement for the USPS to pick up shipments of specific mail classes, such as the First-Class Package International Service. You can schedule a pickup through the Tools menu of your online account.
From the USPS Domestic Mail Manual (01/27/2013):
507
7.2.1 Availability
[1-27-13] Pickup on Demand service is available from designated Post Offices for:
a. Priority Mail Express.
b. Priority Mail.
c. Standard Post. (now Retail Ground--January 2016)
d. Certain types of international mail; see 7.2.8 for more information.
7.2.8 International Mail
[1-27-13] The following types of international mail are available for Pickup on
Demand, including a package pickup (under 7.3.3c), when all eligibility and
preparation standards in the International Mail Manual are met:
a. Global Express Guaranteed.
b. Priority Mail Express International.
c. Priority Mail International.
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